A detailed mathematical analysis of the method is carried out for a charge transfer reaction of the type A − → A + e 0 −. Limitations of the slow and of the fast potential-sweep technique, from the point of view of obtaining kinetic data or coverages in the case of complex reactions ( eg electro-organic oxidations) are discussed. ![]() A comparison is made of the current/time curve obtained by the potential-sweep method and of the potential/time curve obtained galvanostatically.
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